Automatic rule generation based on genetic programming for event correlation

The widespread adoption of autonomous intrusion detection technology is overwhelming current frameworks for network security management. Modern intrusion detection systems (IDSs) and intelligent agents are the most mentioned in literature and news, although other risks such as broad attacks (e.g. very widely spread in a distributed fashion like botnets), and their consequences on incident response management cannot be overlooked. Event correlation becomes then essential. Basically, security event correlation pulls together detection, prevention and reaction tasks by means of consolidating huge amounts of event data. Providing adaptation to unknown distributed attacks is a major requirement as well as their automatic identification. This positioning paper poses an optimization challenge in the design of such correlation engine and a number of directions for research. We present a novel approach for automatic generation of security event correlation rules based on Genetic Programming which has been already used at sensor level

Steganalysis of Hydan

Hydan is a steganographic tool which can be used to hide any kind of information inside executable files. In this work, we present an efficient distinguisher for it: We have developed a system that is able to detect executable files with embedded information through Hydan. Our system uses statistical analysis of instruction set distribution to distinguish between files with no hidden information and files that have been modified with Hydan. We have tested our algorithm against a mix of clean and stego-executable files. The proposed distinguisher is able to tell apart these files with a 0 ratio of false positives and negatives, thus detecting all files with hidden information through Hydan

Enantiopure Double ortho-Oligophenylethynylene-Based Helical Structures with Circularly Polarized Luminescence Activity

In this paper, we describe the optical and chiroptical properties of an enantiopure multipodal ortho-oligophenylethynylene (S,S,S,S)-1 presenting four chiral sulfoxide groups at the extremes. The presence of these groups together with alkynes allows the coordination with carbophilic Ag(I), and/or oxophilic Zn(II) cations, yielding double helical structures in an enantiopure way. In this sense, different behaviors in absorption, fluorescence, ECD and CPL spectra have been found depending on the stoichiometry and nature of the metal. We have observed that Zn(II) coordination favors an intensity increase of the electronic circular dichroism (ECD) spectra of compound (S,S,S,S)-1 yielding an M-helicity in the ortho-oligophenylene ethynylene (o-OPE) backbone. On the other hand, ECD spectra of final Ag(I) complex shows two different bands with an opposite sign to the free ligand, thus giving the P-helical isomer. In addition, circularly polarized luminescence (CPL) exhibit an enhanced intensity and negative sign in both complexes. Computational studies were also carried out, supporting the experimental results

Simple Perylene Diimide Cyclohexane Derivative With Combined CPL and TPA Properties

The Supplementary Material for this article can be found online at: https://www.frontiersin.org/articles/10.3389/fchem. 2020.00306/full#supplementary-materialIn this work we describe the linear and non-linear (chiro)optical properties of an enantiopure bis-perylenediimide (PDI) cyclohexane derivative. This compound exhibits upconversion based on a two-photon absorption (TPA) process with a cross-section value of 70 GM together with emission of circularly polarized luminescence (CPL), showing a glum in the range of 10−3. This simple structure represents one of the scarce examples of purely organic compounds combining both TPA and CPL responses, together with large values of molar absorptivity and fluorescence quantum yield with emission in the 500–600 nm. Self-assembly induced by introduction of a poor solvent allows for a spectacular shift of the emission into the near-infrared (NIR, 650–750 nm) by formation of well-defined rotationally displaced dimers. Therefore, we are here presenting a versatile platform whose optical properties can be simply tuned by self-assembly or by functionalization of the electron-deficient aromatic core of PDIs.Ministerio de Ciencia, Innovacion y Universidades PG2018-101181-B-I00Spanish Government CTQ2017-85454-C2-1-PEuropean Research Council (ERC) ERC-2015-STG-677023MINECO RyC-2013-12943Spanish GovernmentPortuguese Foundation for Science and TechnologyPOCIEuropean Union (EU) PTDC/NAN-MAT/29317/2017 PTDC/QUI-QFI/29319/2017 UIDB/00100/202

Optically active Ag(i):: O-OPE helicates using a single homochiral sulfoxide as chiral inducer

In this work we describe the ability of a simple enantiopure sulfoxide group to promote folding of oligo ortho-phenylene ethynylenes (o-OPEs) with one helical sense. A family of foldamers with up to seven triple bonds was synthesized and fully characterized. Moreover, changes in structure and chiroptical properties caused by Ag(i) coordination have been studied by NMR, UV, VCD and ECD measurements. Quantum mechanical DFT calculations support experimental results